Structure 7114444

7114441 << 7114444 >> 7114446
Original COD entry Download CIF Download DOT

Citation: Barthelet, K.; Riou, D.; F\'erey, G. (2002). [VIII(H2O)]3O(O2CC6H4CO2)3·(Cl, 9H2O) (MIL-59): a rare example of vanadocarboxylate with a magnetically frustrated three-dimensional hybrid framework. Chemical Communications, , pp. 1492-.

Formula: C8 H4 Cl0.33 O8.33 V

Chemical name: ?

Cell parameters:

  • a = 19.29070(10) Å
  • b = 19.29070(10) Å
  • c = 19.29070(10) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C192 H96 O128 V24 (C24 H12 O16 V3)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 5, 4, 18, 12, 20, 20
  • 1, 2, 4, 5, 3, 11, 8, 19, 16, 30
  • 1, 2, 4, 7, 5, 18, 12, 20, 20, 40
  • 1, 5, 6, 14, 10, 18, 16, 20, 14, 42
  • 2, 7, 7, 16, 11, 17, 15, 26, 18, 43
  • 3, 4, 3, 5, 4, 18, 12, 20, 20, 40
  • 3, 4, 5, 3, 11, 8, 19, 16, 30, 25
  • 3, 4, 7, 5, 18, 12, 20, 20, 40, 30
  • 3, 4, 13, 9, 13, 12, 29, 21, 25, 20
  • 3, 6, 5, 12, 8, 19, 16, 30, 25, 35
  • 3, 15, 6, 6, 12, 24, 18, 18, 12, 54
  • 6, 6, 14, 10, 18, 16, 20, 14, 42, 28
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