Structure 7115033

7115022 << 7115033 >> 7115034
Original COD entry Download CIF Download DOT

Citation: Mrotzek, Antje; Iordanidis, Lykourgos; Kanatzidis, Mercouri G. (2001). Cs1--xSn1--xBi9+xSe15 and Cs1.5--3xBi9.5+xSe15: members of the homologous superseries Am[M1+lSe2+l]2m[M1+2l+nSe3+3l+n] (A = alkali metal, M = Sn and Bi) allowing structural evolution in three different dimensions. Chemical Communications, , pp. 1648-.

Formula: Bi9.63 Cs1.11 Se15

Cell parameters:

  • a = 27.547(9) Å
  • b = 4.1620(13) Å
  • c = 14.132(5) Å
  • α = 90.00°
  • β = 103.350(6)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Bi20 Cs4 Se30 (Bi10 Cs2 Se15)

Multiplicity: 1

Coordination sequences:

  • 3, 9, 9, 20, 26, 57, 85, 115, 140, 152
  • 3, 10, 13, 27, 38, 60, 74, 103, 129, 185
  • 3, 12, 21, 38, 44, 80, 75, 113, 113, 151
  • 3, 12, 21, 45, 45, 66, 77, 115, 105, 142
  • 4, 10, 24, 35, 53, 64, 80, 92, 153, 160
  • 5, 6, 14, 17, 37, 53, 85, 112, 134, 157
  • 5, 12, 21, 43, 45, 75, 69, 115, 119, 169
  • 5, 12, 28, 38, 63, 57, 83, 96, 134, 147
  • 5, 17, 24, 44, 47, 73, 76, 115, 106, 149
  • 5, 17, 25, 47, 48, 71, 77, 97, 106, 174
  • 6, 11, 27, 33, 53, 58, 100, 93, 128, 126
  • 6, 14, 28, 33, 60, 60, 98, 95, 134, 135
  • 6, 14, 34, 35, 57, 66, 85, 87, 130, 133
  • 6, 18, 22, 36, 44, 84, 76, 112, 114, 156
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