Structure 7115195

7115194 << 7115195 >> 7115196
Original COD entry Download CIF Download DOT

Citation: Jensen, Paul; Batten, Stuart R.; Fallon, Gary D.; Moubaraki, Boujemaa; Murray, Keith S.; Price, David J. (1999). Structural isomers of M(dca)2 molecule-based magnets. Crystal structure of tetrahedrally coordinated sheet-like \b-Zn(dca)2 and \b-Co/Zn(dca)2, and the octahedrally coordinated rutile-like \a-Co(dca)2, where dca-- = dicyanamide, N(CN)2−, and magnetism of \b-Co(dca)2. Chemical Communications, , pp. 177-.

Formula: C4 N6 Zn

Cell parameters:

  • a = 7.6070(3) Å
  • b = 7.5828(4) Å
  • c = 11.8468(6) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 4

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: C4 N6 Zn (C4 N6 Zn)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 6, 6, 6, 6, 6, 6, 18
  • 2, 2, 4, 4, 6, 6, 6, 6, 12, 12
  • 2, 4, 4, 4, 4, 6, 6, 12, 12, 12
  • 4, 4, 4, 4, 4, 4, 12, 12, 12, 12
span 1 {1 1 1}

CIF datablock 1, entity 2 of 4

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: C4 N6 Zn (C4 N6 Zn)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 6, 6, 6, 6, 6, 6, 18
  • 2, 2, 4, 4, 6, 6, 6, 6, 12, 12
  • 2, 4, 4, 4, 4, 6, 6, 12, 12, 12
  • 4, 4, 4, 4, 4, 4, 12, 12, 12, 12
span 1 {1 1 1}

CIF datablock 2, entity 3 of 4

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: C4 N6 Zn (C4 N6 Zn)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 6, 6, 6, 6, 6, 6, 18
  • 2, 2, 4, 4, 6, 6, 6, 6, 12, 12
  • 2, 4, 4, 4, 4, 6, 6, 12, 12, 12
  • 4, 4, 4, 4, 4, 4, 12, 12, 12, 12
span 1 {1 1 1}

CIF datablock 3, entity 4 of 4

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: C4 N6 Zn (C4 N6 Zn)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 6, 6, 6, 6, 6, 6, 18
  • 2, 2, 4, 4, 6, 6, 6, 6, 12, 12
  • 2, 4, 4, 4, 4, 6, 6, 12, 12, 12
  • 4, 4, 4, 4, 4, 4, 12, 12, 12, 12
span 1 {1 1 1}