Structure 7117298

7117297 << 7117298 >> 7117299
Original COD entry Download CIF Download DOT

Citation: Chao Huang; Jie Wu; Chuanjun Song; Ran Ding; Yan Qiao; Hongwei Hou; Junbiao Chang; Yaoting Fan (2015). Reversible conversion of valence-tautomeric copper metal-organic frameworks dependent single-crystal-to-single-crystal oxidation/reduction: a redox-switchable catalyst for C-H bonds activation reaction. Chem.Commun., 51, pp. 10353-.

Formula: C6 H4 Cu2 N9 O1.5

Chemical name: Cu(I)Cu(II) complex

Cell parameters:

  • a = 24.338(5) Å
  • b = 9.4877(19) Å
  • c = 16.502(3) Å
  • α = 90.00°
  • β = 119.89(3)°
  • γ = 90.00°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: C48 H8 Cu16 N72 (C6 H Cu2 N9)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 7, 11, 12, 20, 28, 33, 47
  • 2, 4, 7, 14, 15, 16, 30, 42, 47, 61
  • 2, 4, 7, 14, 15, 17, 27, 41, 45, 61
  • 2, 4, 9, 14, 19, 24, 35, 37, 46, 71
  • 2, 4, 9, 16, 17, 24, 31, 39, 49, 68
  • 3, 4, 7, 11, 12, 20, 28, 33, 47, 72
  • 3, 5, 9, 13, 14, 18, 28, 43, 55, 63
  • 3, 5, 9, 13, 14, 19, 29, 42, 48, 65
  • 3, 6, 8, 9, 15, 20, 26, 37, 54, 73
  • 3, 6, 8, 9, 15, 20, 27, 38, 51, 68
  • 3, 6, 9, 13, 17, 26, 36, 42, 51, 70
  • 3, 6, 9, 13, 18, 23, 33, 38, 53, 69
  • 3, 7, 10, 13, 16, 24, 38, 44, 49, 71
  • 3, 7, 10, 14, 16, 22, 32, 42, 59, 73
  • 3, 7, 10, 14, 17, 23, 33, 37, 57, 76
  • 3, 7, 10, 15, 16, 24, 32, 41, 49, 72
  • 4, 7, 9, 12, 22, 30, 29, 42, 61, 65
  • 4, 7, 11, 12, 22, 24, 27, 43, 63, 77
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