Structure 7122654

7122621 << 7122654 >> 7122664
Original COD entry Download CIF Download DOT

Citation: Zheng, Yu-Jun; Shi, Yong-Fang; Tian, Chong-Bin; Lin, Hua; Wu, Li-Ming; WU, XIN-TAO; Zhu, Qi-Long (2018). An Unprecedented Pentanary Chalcohalide with the Mn Atoms in Two Chemical Environments: Unique Bonding Characteristics and Magnetic Properties. Chemical Communications, , pp. -.

Formula: Cl Cs2 Ga3 Mn2 S7

Cell parameters:

  • a = 6.2467(6) Å
  • b = 7.3879(8) Å
  • c = 33.600(3) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cl2 Ga6 Mn4 S14 (Cl Ga3 Mn2 S7)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 6, 15, 18, 35, 32, 66, 54, 93
  • 2, 6, 9, 21, 22, 42, 38, 72, 53, 92
  • 3, 9, 11, 23, 23, 51, 44, 76, 61, 111
  • 3, 9, 11, 25, 25, 48, 43, 83, 60, 101
  • 3, 9, 12, 25, 23, 48, 44, 80, 58, 106
  • 3, 9, 12, 25, 24, 50, 42, 74, 56, 98
  • 4, 6, 15, 18, 35, 32, 66, 54, 93, 66
  • 4, 6, 15, 18, 36, 32, 62, 50, 86, 64
  • 4, 7, 16, 17, 37, 34, 64, 52, 94, 67
  • 4, 8, 19, 18, 37, 36, 68, 50, 88, 66
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Cl2 Ga6 Mn4 S14 (Cl Ga3 Mn2 S7)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 6, 15, 18, 35, 32, 66, 54, 93
  • 2, 6, 9, 21, 22, 42, 38, 72, 53, 92
  • 3, 9, 11, 23, 23, 51, 44, 76, 61, 111
  • 3, 9, 11, 25, 25, 48, 43, 83, 60, 101
  • 3, 9, 12, 25, 23, 48, 44, 80, 58, 106
  • 3, 9, 12, 25, 24, 50, 42, 74, 56, 98
  • 4, 6, 15, 18, 35, 32, 66, 54, 93, 66
  • 4, 6, 15, 18, 36, 32, 62, 50, 86, 64
  • 4, 7, 16, 17, 37, 34, 64, 52, 94, 67
  • 4, 8, 19, 18, 37, 36, 68, 50, 88, 66
span 1 {1 1 1}