Structure 7125736

7125728 << 7125736 >> 7125779
Original COD entry Download CIF Download DOT

Citation: Huang, Shan-Lin; He, Liang; Chen, Er-Xia; Lai, Heng-Dong; Zhang, Jian; Lin, Qipu (2019). A wide pH-range stable crystalline framework based on the largest tin-oxysulfide cluster [Sn20O10S34].. Chemical communications (Cambridge, England), 55, pp. 11083-11086.

Formula: C48 H133 N9 O23 S32 Sn20

Chemical name: 3D-T4-SnOS

Cell parameters:

  • a = 23.5105(4) Å
  • b = 23.5105(4) Å
  • c = 40.205(3) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: O40 S128 Sn80 (O5 S16 Sn10)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 6, 20, 12, 30, 20, 30, 6, 18
  • 2, 8, 6, 16, 12, 27, 11, 23, 15, 31
  • 2, 9, 8, 18, 8, 17, 10, 25, 14, 36
  • 3, 12, 7, 16, 11, 18, 6, 19, 15, 45
  • 3, 12, 9, 20, 8, 13, 6, 17, 13, 38
  • 4, 4, 13, 9, 25, 16, 30, 13, 24, 12
  • 4, 15, 12, 23, 6, 11, 8, 26, 18, 50
  • 6, 6, 16, 10, 20, 8, 18, 11, 31, 22
  • 6, 9, 24, 9, 13, 4, 10, 10, 33, 21
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CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: O40 S128 Sn80 (O5 S16 Sn10)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 6, 20, 12, 30, 20, 30, 6, 18
  • 2, 8, 6, 16, 12, 27, 11, 23, 15, 31
  • 2, 9, 8, 18, 8, 17, 10, 25, 14, 36
  • 3, 12, 7, 16, 11, 18, 6, 19, 15, 45
  • 3, 12, 9, 20, 8, 13, 6, 17, 13, 38
  • 4, 4, 13, 9, 25, 16, 30, 13, 24, 12
  • 4, 15, 12, 23, 6, 11, 8, 26, 18, 50
  • 6, 6, 16, 10, 20, 8, 18, 11, 31, 22
  • 6, 9, 24, 9, 13, 4, 10, 10, 33, 21
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