Structure 7204863

7204862 << 7204863 >> 7204868
Original COD entry Download CIF Download DOT

Citation: Yan, Bangbo; Goh, Ngoh K.; Chia, Lian S.; Stucky, Galen D. (2004). Hydrothermal synthesis, structures and catalytic properties of the new open-framework cobalt tungsten phosphates (enH2)3[Co3W4P4O28] and K6[Co3W4P4O28]�4H2O. Journal of Materials Chemistry, 14, pp. 1567-.

Formula: Co3 H8 K6 O32 P4 W4

Cell parameters:

  • a = 16.960(5) Å
  • b = 16.960(5) Å
  • c = 10.705(5) Å
  • α = 90.00°
  • β = 90.00°
  • γ = 90.00°

List type: interleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 3

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Co12 O112 P16 W16 (Co3 O28 P4 W4)

Multiplicity: 1

Coordination sequences:

  • 2, 6, 6, 21, 18, 66, 44, 129, 62, 187
  • 2, 8, 6, 20, 16, 52, 38, 119, 64, 192
  • 2, 8, 6, 20, 16, 52, 39, 123, 64, 190
  • 2, 10, 8, 25, 18, 59, 42, 126, 69, 208
  • 2, 10, 8, 25, 18, 59, 42, 126, 69, 209
  • 2, 10, 8, 25, 18, 59, 42, 128, 72, 213
  • 4, 4, 12, 12, 48, 36, 112, 48, 140, 90
  • 4, 4, 15, 12, 39, 30, 101, 54, 158, 89
  • 6, 6, 20, 14, 46, 34, 104, 58, 176, 102
  • 6, 6, 20, 14, 46, 34, 105, 61, 183, 102
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CIF datablock 1, entity 2 of 3

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: K40 O16 (K5 O2)

Multiplicity: 1

Coordination sequences:

  • 2, 4, 4, 6, 6, 10, 9, 15, 18, 17
  • 3, 4, 4, 8, 7, 9, 13, 12, 20, 21
  • 3, 4, 7, 5, 8, 13, 9, 14, 21, 23
  • 3, 5, 5, 5, 7, 11, 12, 13, 21, 22
  • 3, 6, 4, 7, 10, 8, 13, 16, 18, 22
  • 4, 4, 5, 8, 8, 9, 14, 14, 19, 23
  • 5, 3, 5, 7, 9, 8, 12, 20, 14, 22
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CIF datablock 2, entity 3 of 3

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: K40 O16 (K5 O2)

Multiplicity: 1

Coordination sequences:

  • 2, 4, 4, 6, 6, 10, 9, 15, 18, 17
  • 3, 4, 4, 8, 7, 9, 13, 12, 20, 21
  • 3, 4, 7, 5, 8, 13, 9, 14, 21, 23
  • 3, 5, 5, 5, 7, 11, 12, 13, 21, 22
  • 3, 6, 4, 7, 10, 8, 13, 16, 18, 22
  • 4, 4, 5, 8, 8, 9, 14, 14, 19, 23
  • 5, 3, 5, 7, 9, 8, 12, 20, 14, 22
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