Structure 7223456

7223454 << 7223456 >> 7223458
Original COD entry Download CIF Download DOT

Citation: Guo, Hai-Yang; Li, Zhi-Fang; Zhang, Xiao; Fu, Li-Wei; Hu, Yang-Yang; Guo, Lan-Lan; Cui, Xiao-Bing; Huo, Qi-Sheng; Xu, Ji-Qing (2016). New self-assembly hybrid compounds based on arsenic--vanadium clusters and transition metal mixed-organic-ligand complexes. CrystEngComm, 18, pp. 566-.

Formula: C48 H46 As8 N18 Ni5 O43 V14

Cell parameters:

  • a = 14.861(3) Å
  • b = 14.142(3) Å
  • c = 22.798(5) Å
  • α = 90°
  • β = 106.37(3)°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0.5)

Dimensionality: 1

Formula: C24 H4 As16 N8 Ni4 O84 V28 (C6 H As4 N2 Ni O21 V7)

span 1 {1 1 1}

CIF datablock 3, entity 4 of 2

Basis: (0;0;1)

Dimensionality: 1

Formula: C12 H12 N8 Ni4 (C3 H3 N2 Ni)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 4, 3, 3, 6, 6, 3, 3, 6
  • 1, 2, 4, 4, 4, 8, 4, 2, 4, 8
  • 2, 4, 8, 4, 2, 4, 8, 4, 2, 4
  • 3, 4, 3, 3, 6, 6, 3, 3, 6, 6
  • 3, 4, 4, 4, 8, 4, 2, 4, 8, 4
  • 3, 5, 4, 5, 4, 5, 4, 5, 4, 5
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