Structure 7231927

7231916 << 7231927 >> 7231947
Original COD entry Download CIF Download DOT

Citation: Tanaka, Koichi; Kawakita, Tomohiro; Morawiak, Maja; Urbanczyk-Lipkowska, Zofia (2019). A novel homochiral metal--organic framework with an expanded open cage based on (R)-3,3′-bis(6-carboxy-2-naphthyl)-2,2′-dihydroxy-1,1′-binaphthyl: synthesis, X-ray structure and efficient HPLC enantiomer separation. CrystEngComm, 21, pp. 487-.

Formula: C101 H86 Cu2 N5 O21

Cell parameters:

  • a = 22.4236(8) Å
  • b = 29.6641(11) Å
  • c = 15.5246(6) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 4

Basis: (1;0;0)

Dimensionality: 1

Formula: C90 H62 Cu2 N2 O14 (C45 H31 Cu N O7)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 4

Basis: (1;0;0)

Dimensionality: 1

Formula: C90 H62 Cu2 N2 O14 (C45 H31 Cu N O7)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 2, entity 3 of 4

Basis: (1;0;0)

Dimensionality: 1

Formula: C90 H62 Cu2 N2 O14 (C45 H31 Cu N O7)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 3, entity 4 of 4

Basis: (1;0;0)

Dimensionality: 1

Formula: C90 H62 Cu2 N2 O14 (C45 H31 Cu N O7)

Multiplicity: 1

span 1 {1 1 1}