Structure 7234379

7234349 << 7234379 >> 7234397
Original COD entry Download CIF Download DOT

Citation: Alexandre Abherve; Mario Palacios-Corella; Juan Modesto Clemente-Juan; Raphael Marx; Petr Neugebauer; Joris van Slageren; Miguel Clemente-Leon; Eugenio Coronado (2015). Bimetallic MnIII-FeII hybrid complexes formed by a functionalized MnIII Anderson polyoxometalate coordinated to FeII: observation of a field-induced slow relaxation of magnetization in the MnIII centres and a photoinduced spin-crossover in the FeII centres. Journal of Materials Chemistry C, 3, pp. 7936-7945.

Formula: C38 H44 Fe2 Mn Mo6 N14 O32

Cell parameters:

  • a = 24.221(5) Å
  • b = 16.600(3) Å
  • c = 16.512(3) Å
  • α = 90°
  • β = 97.76(2)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: C76 H100 Fe4 Mn2 Mo12 N28 O60 (C38 H50 Fe2 Mn Mo6 N14 O30)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: C76 H100 Fe4 Mn2 Mo12 N28 O60 (C38 H50 Fe2 Mn Mo6 N14 O30)

Multiplicity: 1

span 1 {1 1 1}