Structure 7238025

7238000 << 7238025 >> 7238026
Original COD entry Download CIF Download DOT

Citation: Yao, Zhi-Yuan; Qian, Yin; Ren, Qiu; Zhang, Guo-Qin; Zhang, Jin; Liu, Wen-Long; Luo, Hong-Bin; Ren, Xiao-Ming (2019). Order--disorder transformation of intercalated cations triggering huge negative thermal expansion, switchable dielectrics and ion conduction near room temperature in a 2D vanadium oxide hybrid. Journal of Materials Chemistry C, 7, pp. 13243-.

Formula: C3 H12 N2 O10 V4

Cell parameters:

  • a = 8.0052(8) Å
  • b = 10.0066(9) Å
  • c = 15.6982(14) Å
  • α = 90°
  • β = 100.691(4)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: O20 V8 (O5 V2)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 4, 15, 10, 27, 14, 39, 18, 49
  • 1, 4, 5, 15, 9, 27, 14, 38, 19, 51
  • 2, 7, 7, 21, 12, 33, 16, 44, 21, 56
  • 3, 10, 7, 21, 11, 32, 17, 45, 21, 56
  • 4, 4, 15, 10, 27, 14, 39, 18, 49, 24
  • 5, 5, 15, 9, 27, 14, 38, 19, 51, 23
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: O20 V8 (O5 V2)

Multiplicity: 1

Coordination sequences:

  • 1, 3, 4, 15, 10, 27, 14, 39, 18, 49
  • 1, 4, 5, 15, 9, 27, 14, 38, 19, 51
  • 2, 7, 7, 21, 12, 33, 16, 44, 21, 56
  • 3, 10, 7, 21, 11, 32, 17, 45, 21, 56
  • 4, 4, 15, 10, 27, 14, 39, 18, 49, 24
  • 5, 5, 15, 9, 27, 14, 38, 19, 51, 23
span 1 {1 1 1}