Structure 7239740

7239732 << 7239740 >> 7239741

Citation: Usman, Mohammad; Smith, Mark D.; Kocevski, Vancho; Besmann, Theodore; zur Loye, Hans-Conrad (2020). Complex cobalt silicates and germanates crystallizing in a porous three-dimensional framework structure. CrystEngComm, 22, pp. 1112-1119.

Formula: Co0.69 Cs1.29 Ge1.81 O5

Cell parameters:

a = 7.4239(14) Å
b = 7.4239(14) Å
c = 13.169(3) Å

α = 90°
β = 90°
γ = 90°

List type: interleaving

List: 3D

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Co10 Ge10 O20 (Co Ge O2)

Multiplicity: 1

span 1 {1 1 1}

highlight edges

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Cs40 (Cs)

Multiplicity: 1

Coordination sequences:

11, 34, 70, 162, 248, 345, 507, 670, 834, 1034
12, 31, 62, 140, 240, 327, 478, 639, 828, 964
12, 35, 72, 153, 252, 353, 493, 653, 856, 1036
15, 26, 68, 143, 221, 360, 480, 633, 817, 1072
15, 31, 67, 156, 244, 341, 516, 648, 819, 1080
17, 31, 77, 173, 220, 383, 515, 617, 890, 1070