Structure 7241291

7241290 << 7241291 >> 7241292
Original COD entry Download CIF Download DOT

Citation: Tian, Xin-Yu; Du, Cui-Xia; ZhaoRi, GeTu; SheLe, MuGe; Bao, Yongsheng; Baiyin, Menghe (2020). The solvothermal synthesis and characterization of quaternary arsenic chalcogenides CsTMAsQ3 (TM = Hg, Cd; Q = S, Se) using Cs+ as a structure directing agent: from 1D anionic chains to 2D anionic layers. RSC Advances, 10, pp. 34903-34909.

Formula: As Cs Hg Se3

Cell parameters:

  • a = 6.957(5) Å
  • b = 14.917(11) Å
  • c = 7.415(6) Å
  • α = 90.00°
  • β = 96.926(13)°
  • γ = 90.00°

List type: interleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: As2 Hg2 Se6 (As Hg Se3)

Multiplicity: 1

Coordination sequences:

  • 2, 5, 7, 14, 12, 21, 16, 28, 21, 35
  • 3, 4, 11, 10, 17, 14, 25, 18, 31, 24
  • 3, 7, 7, 14, 11, 21, 17, 28, 21, 35
  • 4, 5, 10, 9, 18, 14, 24, 19, 32, 23
span 1 {1 1 1}

CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: As2 Hg2 Se6 (As Hg Se3)

Multiplicity: 1

Coordination sequences:

  • 2, 5, 7, 14, 12, 21, 16, 28, 21, 35
  • 3, 4, 11, 10, 17, 14, 25, 18, 31, 24
  • 3, 7, 7, 14, 11, 21, 17, 28, 21, 35
  • 4, 5, 10, 9, 18, 14, 24, 19, 32, 23
span 1 {1 1 1}