Structure 7241292

7241291 << 7241292 >> 7241293
Original COD entry Download CIF Download DOT

Citation: Tian, Xin-Yu; Du, Cui-Xia; ZhaoRi, GeTu; SheLe, MuGe; Bao, Yongsheng; Baiyin, Menghe (2020). The solvothermal synthesis and characterization of quaternary arsenic chalcogenides CsTMAsQ3 (TM = Hg, Cd; Q = S, Se) using Cs+ as a structure directing agent: from 1D anionic chains to 2D anionic layers. RSC Advances, 10, pp. 34903-34909.

Formula: As2 Cs2 Hg2 S6

Cell parameters:

  • a = 10.090(2) Å
  • b = 6.6510(16) Å
  • c = 10.428(3) Å
  • α = 90.00°
  • β = 94.686(4)°
  • γ = 90.00°

List type: noninterleaving

List: 2D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;1 0;1;0)

Dimensionality: 2

Formula: As4 Hg4 S12 (As Hg S3)

Coordination sequences:

  • 2, 5, 7, 15, 13, 23, 18, 30, 23, 38
  • 2, 5, 8, 16, 14, 24, 18, 31, 24, 40
  • 3, 4, 11, 12, 21, 16, 27, 20, 35, 28
  • 3, 8, 8, 15, 13, 23, 19, 32, 24, 40
  • 4, 6, 12, 10, 19, 16, 28, 22, 36, 26
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