Structure 7704691

7704690 << 7704691 >> 7704693

Citation: Yan, Dongming; Xiao, Yu; Liu, Chang; Hou, Peipei; Chai, Wenxiang; Hosono, Hideo; Lin, Hua; Liu, Yi (2020). Two new members in the quaternary Cs-Ag-As-S family with different arrangements of Ag-S and As-S asymmetric building units: syntheses, structures, and theoretical studies.. Dalton transactions (Cambridge, England : 2003), 49, pp. 9743-9750.

Formula: Ag As4 Cs3 S8

Cell parameters:

a = 27.760(6) Å
b = 6.9800(14) Å
c = 19.680(4) Å

α = 90°
β = 109.85(3)°
γ = 90°

List type: interleaving

List: 2D

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;1;0)

Dimensionality: 2

Formula: Ag4 As16 S32 (Ag As4 S8)

Multiplicity: 1

Coordination sequences:

1, 2, 2, 4, 4, 8, 10, 23, 22, 35
1, 2, 2, 4, 4, 10, 12, 21, 24, 35
2, 4, 2, 4, 6, 14, 16, 30, 28, 38
2, 4, 4, 8, 8, 17, 16, 30, 28, 39
2, 4, 4, 10, 10, 17, 20, 28, 30, 39
2, 4, 5, 11, 11, 21, 17, 27, 31, 38
3, 2, 4, 4, 8, 10, 23, 22, 35, 34
3, 2, 4, 4, 10, 12, 21, 24, 35, 34
3, 4, 8, 8, 17, 14, 24, 24, 36, 35
3, 4, 10, 10, 17, 18, 24, 28, 34, 37
3, 7, 8, 16, 14, 24, 22, 32, 31, 41
3, 9, 10, 16, 18, 24, 26, 32, 35, 39
5, 7, 12, 15, 21, 20, 29, 31, 34, 39
5, 7, 14, 13, 19, 24, 27, 29, 36, 39

span 1 {1 1 1}

highlight edges

CIF datablock 1, entity 2 of 2