Structure 7707082

7707077 << 7707082 >> 7707083
Original COD entry Download CIF Download DOT

Citation: Akopov, Georgiy; Mark, Justin; Viswanathan, Gayatri; Lee, Shannon J.; McBride, Brennan C.; Won, Juyeon; Perras, Fr\'ed\'eric A; Paterson, Alexander L.; Yuan, Bing; Sen, Sabyasachi; Adeyemi, Adedoyin N.; Zhang, Feng; Wang, Cai-Zhuang; Ho, Kai-Ming; Miller, Gordon J.; Kovnir, Kirill (2021). Third time's the charm: intricate non-centrosymmetric polymorphism in LnSiP3 (Ln = La and Ce) induced by distortions of phosphorus square layers.. Dalton transactions (Cambridge, England : 2003), 50, pp. 6463-6476.

Formula: La P3 Si

Cell parameters:

  • a = 5.9650(2) Å
  • b = 25.2125(10) Å
  • c = 5.8168(2) Å
  • α = 90°
  • β = 90°
  • γ = 90°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: La8 P56 Si16 (La P7 Si2)

Multiplicity: 1

Coordination sequences:

  • 6, 46, 83, 179, 255, 400, 459, 751, 803, 1156
  • 7, 18, 72, 118, 254, 342, 506, 550, 923, 984
  • 7, 26, 57, 149, 219, 370, 451, 691, 750, 1136
  • 7, 31, 73, 139, 202, 327, 462, 634, 826, 1000
  • 8, 30, 65, 127, 184, 315, 424, 614, 778, 968
  • 9, 21, 65, 113, 198, 247, 450, 542, 784, 934
  • 11, 41, 83, 160, 215, 378, 478, 700, 842, 1078
  • 14, 39, 107, 160, 279, 338, 573, 664, 923, 1013
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