Structure 7708977

7708954 << 7708977 >> 7708978
Original COD entry Download CIF Download DOT

Citation: Deyneko, Dina V.; Nikiforov, Ivan V.; Lazoryak, Bogdan I.; Aksenov, Sergey (2021). The role of anionic heterovalent [PO4]3-- \\rightarrow [GeO4]4-- substitution on the luminescent properties in inorganic phosphors with the \b-Ca3(PO4)2 type structure: New data based on accurate crystal structure refinement. Dalton Transactions, , pp. -.

Formula: Ca48.6 Eu5.999 Ge1.198 O168 P40.799 Zn6

Cell parameters:

  • a = 10.374860(15) Å
  • b = 10.374860(15) Å
  • c = 37.152960(75) Å
  • α = 90°
  • β = 90°
  • γ = 120°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Ca54 Eu54 Ge18 O168 P42 Zn6 (Ca9 Eu9 Ge3 O28 P7 Zn)

Multiplicity: 1

Coordination sequences:

  • 1, 18, 70, 204, 421, 672, 1027, 1551, 1972, 2600
  • 2, 19, 75, 200, 429, 711, 1056, 1538, 2043, 2644
  • 3, 31, 107, 271, 495, 775, 1195, 1698, 2155, 2842
  • 3, 32, 97, 261, 494, 760, 1181, 1682, 2138, 2825
  • 3, 32, 115, 265, 517, 843, 1247, 1684, 2304, 2888
  • 4, 9, 90, 193, 457, 681, 1041, 1579, 2028, 2605
  • 4, 40, 138, 310, 529, 852, 1257, 1813, 2295, 2912
  • 4, 41, 131, 293, 562, 841, 1263, 1790, 2316, 2927
  • 4, 42, 125, 312, 535, 881, 1292, 1762, 2338, 3011
  • 4, 43, 128, 300, 555, 866, 1269, 1803, 2287, 2989
  • 4, 45, 121, 303, 574, 870, 1311, 1815, 2333, 3024
  • 5, 37, 140, 286, 510, 902, 1255, 1688, 2374, 2899
  • 5, 42, 115, 280, 528, 828, 1227, 1740, 2229, 2946
  • 5, 42, 135, 308, 548, 877, 1322, 1754, 2366, 2994
  • 7, 42, 133, 306, 569, 888, 1255, 1833, 2339, 2971
  • 9, 38, 135, 308, 548, 877, 1322, 1754, 2366, 2994
  • 9, 49, 164, 325, 605, 944, 1377, 1849, 2459, 3101
  • 12, 81, 211, 379, 638, 1073, 1413, 1998, 2578, 3199
  • 18, 69, 182, 408, 687, 1024, 1482, 2011, 2589, 3270
  • 19, 70, 204, 421, 672, 1027, 1551, 1972, 2600, 3337
  • 19, 82, 216, 409, 723, 1102, 1487, 2056, 2683, 3296
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