Structure 7708978

7708977 << 7708978 >> 7708979
Original COD entry Download CIF Download DOT

Citation: Deyneko, Dina V.; Nikiforov, Ivan V.; Lazoryak, Bogdan I.; Aksenov, Sergey (2021). The role of anionic heterovalent [PO4]3-- \\rightarrow [GeO4]4-- substitution on the luminescent properties in inorganic phosphors with the \b-Ca3(PO4)2 type structure: New data based on accurate crystal structure refinement. Dalton Transactions, , pp. -.

Formula: Ca49.799 Eu6.001 Ge3.6 O168 P38.4 Zn6

Cell parameters:

  • a = 10.428770(27) Å
  • b = 10.428770(27) Å
  • c = 37.34327(14) Å
  • α = 90°
  • β = 90°
  • γ = 120°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Ca54 Eu54 Ge18 O168 P42 Zn6 (Ca9 Eu9 Ge3 O28 P7 Zn)

Multiplicity: 1

Coordination sequences:

  • 1, 16, 61, 171, 367, 617, 913, 1334, 1736, 2296
  • 2, 17, 72, 175, 371, 643, 929, 1326, 1783, 2282
  • 2, 27, 91, 231, 449, 690, 1022, 1505, 1852, 2483
  • 3, 30, 88, 233, 450, 686, 1022, 1505, 1852, 2483
  • 3, 31, 99, 232, 464, 725, 1050, 1507, 1927, 2487
  • 4, 9, 87, 169, 418, 615, 948, 1354, 1773, 2209
  • 4, 37, 128, 296, 472, 797, 1151, 1574, 2047, 2590
  • 4, 38, 141, 270, 476, 815, 1135, 1553, 2088, 2598
  • 4, 40, 117, 264, 491, 781, 1090, 1571, 1984, 2613
  • 4, 40, 119, 274, 505, 767, 1127, 1580, 2008, 2594
  • 4, 41, 106, 271, 499, 785, 1123, 1534, 2029, 2564
  • 4, 48, 139, 285, 523, 846, 1197, 1578, 2114, 2700
  • 5, 40, 115, 269, 491, 794, 1138, 1533, 2022, 2622
  • 5, 40, 118, 270, 498, 772, 1126, 1555, 2036, 2563
  • 6, 30, 113, 257, 488, 782, 1083, 1571, 2008, 2581
  • 7, 39, 126, 271, 508, 812, 1139, 1588, 2037, 2615
  • 9, 49, 161, 304, 569, 886, 1232, 1671, 2187, 2715
  • 12, 78, 211, 361, 578, 1010, 1260, 1836, 2257, 2950
  • 17, 61, 171, 367, 617, 913, 1334, 1736, 2296, 2829
  • 18, 67, 174, 369, 629, 916, 1314, 1769, 2270, 2852
  • 18, 70, 179, 375, 627, 920, 1357, 1740, 2310, 2880
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