Structure 7708979

7708978 << 7708979 >> 7708980
Original COD entry Download CIF Download DOT

Citation: Deyneko, Dina V.; Nikiforov, Ivan V.; Lazoryak, Bogdan I.; Aksenov, Sergey (2021). The role of anionic heterovalent [PO4]3-- \\rightarrow [GeO4]4-- substitution on the luminescent properties in inorganic phosphors with the \b-Ca3(PO4)2 type structure: New data based on accurate crystal structure refinement. Dalton Transactions, , pp. -.

Formula: Ca49.2 Eu5.997 Ge2.399 O168 P39.598 Zn6

Cell parameters:

  • a = 10.388380(10) Å
  • b = 10.388380(10) Å
  • c = 37.223810(56) Å
  • α = 90°
  • β = 90°
  • γ = 120°

List type: noninterleaving

List: 3D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 1

Basis: (1;0;0 0;1;0 0;0;1)

Dimensionality: 3

Formula: Ca54 Eu54 Ge18 O168 P42 Zn6 (Ca9 Eu9 Ge3 O28 P7 Zn)

Multiplicity: 1

Coordination sequences:

  • 1, 18, 65, 170, 356, 584, 853, 1221, 1600, 2102
  • 2, 17, 73, 165, 342, 613, 892, 1227, 1640, 2116
  • 2, 27, 81, 212, 415, 655, 924, 1344, 1712, 2233
  • 3, 29, 91, 210, 416, 700, 996, 1312, 1813, 2269
  • 3, 30, 77, 212, 415, 655, 924, 1344, 1712, 2233
  • 4, 9, 84, 145, 394, 612, 873, 1189, 1746, 2041
  • 4, 36, 132, 268, 436, 736, 1108, 1380, 1898, 2379
  • 4, 38, 110, 242, 467, 713, 1020, 1415, 1841, 2312
  • 4, 39, 104, 257, 454, 729, 1006, 1428, 1847, 2344
  • 4, 40, 111, 262, 467, 748, 1044, 1442, 1842, 2406
  • 4, 40, 133, 271, 455, 739, 1087, 1440, 1893, 2420
  • 4, 45, 109, 240, 475, 744, 1092, 1437, 1931, 2436
  • 5, 40, 108, 241, 460, 749, 1035, 1436, 1849, 2391
  • 5, 41, 120, 261, 470, 758, 1069, 1421, 1890, 2429
  • 7, 39, 120, 261, 470, 758, 1069, 1421, 1890, 2429
  • 7, 41, 124, 260, 470, 794, 1055, 1445, 1910, 2429
  • 8, 38, 126, 258, 474, 784, 1102, 1436, 1936, 2412
  • 12, 81, 202, 352, 530, 911, 1209, 1617, 2053, 2668
  • 17, 60, 166, 336, 579, 854, 1199, 1596, 2094, 2581
  • 17, 63, 152, 327, 591, 857, 1158, 1621, 2045, 2608
  • 19, 65, 170, 356, 584, 853, 1221, 1600, 2102, 2592
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