Structure 7709147

7709140 << 7709147 >> 7709148
Original COD entry Download CIF Download DOT

Citation: Liu, Chang; Yang, He-Di; Hou, Pei-Pei; Xiao, Yu; Liu, Yi; Lin, Hua (2022). Cs3CuAs4Q8 (Q = S, Se): unique two-dimensional layered inorganic thioarsenates with the lowest Cu-to-As ratio and remarkable photocurrent responses. Dalton Transactions, , pp. -.

Formula: As4 Cs3 Cu S8

Cell parameters:

  • a = 24.203(2) Å
  • b = 7.7320(3) Å
  • c = 21.9290(16) Å
  • α = 90°
  • β = 116.143(10)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: As16 Cu4 S32 (As4 Cu S8)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 2, 4, 4, 11, 13, 6, 6, 10
  • 2, 4, 3, 7, 9, 9, 9, 8, 7, 10
  • 2, 4, 3, 8, 8, 8, 10, 8, 7, 10
  • 2, 6, 7, 7, 4, 6, 7, 9, 13, 13
  • 2, 6, 7, 7, 4, 6, 7, 10, 12, 12
  • 2, 6, 8, 4, 4, 7, 5, 7, 8, 18
  • 3, 2, 4, 4, 11, 13, 6, 6, 10, 8
  • 3, 3, 7, 8, 5, 5, 11, 10, 8, 9
  • 3, 3, 8, 7, 5, 5, 10, 11, 8, 9
  • 5, 8, 6, 4, 6, 6, 6, 8, 15, 24
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CIF datablock 1, entity 2 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: As16 Cu4 S32 (As4 Cu S8)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 2, 4, 4, 11, 13, 6, 6, 10
  • 2, 4, 3, 7, 9, 9, 9, 8, 7, 10
  • 2, 4, 3, 8, 8, 8, 10, 8, 7, 10
  • 2, 6, 7, 7, 4, 6, 7, 9, 13, 13
  • 2, 6, 7, 7, 4, 6, 7, 10, 12, 12
  • 2, 6, 8, 4, 4, 7, 5, 7, 8, 18
  • 3, 2, 4, 4, 11, 13, 6, 6, 10, 8
  • 3, 3, 7, 8, 5, 5, 11, 10, 8, 9
  • 3, 3, 8, 7, 5, 5, 10, 11, 8, 9
  • 5, 8, 6, 4, 6, 6, 6, 8, 15, 24
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