Structure 7709148

7709147 << 7709148 >> 7709159
Original COD entry Download CIF Download DOT

Citation: Liu, Chang; Yang, He-Di; Hou, Pei-Pei; Xiao, Yu; Liu, Yi; Lin, Hua (2022). Cs3CuAs4Q8 (Q = S, Se): unique two-dimensional layered inorganic thioarsenates with the lowest Cu-to-As ratio and remarkable photocurrent responses. Dalton Transactions, , pp. -.

Formula: As4 Cs3 Cu Se8

Cell parameters:

  • a = 24.856(5) Å
  • b = 8.0456(16) Å
  • c = 22.602(5) Å
  • α = 90°
  • β = 116.93(3)°
  • γ = 90°

List type: interleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: As16 Cu4 Se32 (As4 Cu Se8)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 2, 4, 4, 9, 11, 9, 6, 10
  • 2, 4, 3, 6, 6, 11, 10, 8, 6, 11
  • 2, 4, 3, 7, 9, 7, 7, 11, 7, 10
  • 2, 5, 5, 7, 6, 6, 6, 10, 12, 11
  • 2, 5, 6, 6, 6, 6, 6, 9, 9, 15
  • 2, 6, 8, 4, 4, 7, 5, 7, 8, 16
  • 3, 2, 4, 4, 9, 11, 9, 6, 10, 7
  • 3, 3, 6, 5, 8, 5, 10, 10, 9, 8
  • 3, 3, 7, 8, 5, 5, 9, 8, 11, 9
  • 4, 6, 6, 6, 6, 5, 7, 7, 13, 17
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CIF datablock 1, entity 2 of 2

Basis: (0;1;0 0;0;1)

Dimensionality: 2

Formula: As16 Cu4 Se32 (As4 Cu Se8)

Multiplicity: 1

Coordination sequences:

  • 1, 2, 2, 4, 4, 9, 11, 9, 6, 10
  • 2, 4, 3, 6, 6, 11, 10, 8, 6, 11
  • 2, 4, 3, 7, 9, 7, 7, 11, 7, 10
  • 2, 5, 5, 7, 6, 6, 6, 10, 12, 11
  • 2, 5, 6, 6, 6, 6, 6, 9, 9, 15
  • 2, 6, 8, 4, 4, 7, 5, 7, 8, 16
  • 3, 2, 4, 4, 9, 11, 9, 6, 10, 7
  • 3, 3, 6, 5, 8, 5, 10, 10, 9, 8
  • 3, 3, 7, 8, 5, 5, 9, 8, 11, 9
  • 4, 6, 6, 6, 6, 5, 7, 7, 13, 17
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