Structure 8100590

8100589 << 8100590 >> 8100591
Original COD entry Download CIF Download DOT

Citation: Pilet, Guillaume; Hernandez, Olivier; Perrin, Andre (2002). Crystal structure of rhenium caesium sulfobromide, CsRe~6~S~8~Br~3~, the first cluster compound in the Cs-Re-S-Br system exhibiting two types of inter-unit bridges. Zeitschrift f\"ur Kristallographie - New Crystal Structures, 217, pp. 11-12.

Formula: Br3 Cs Re6 S8

Cell parameters:

  • a = 6.3481(1) Å
  • b = 18.5504(3) Å
  • c = 15.0706(2) Å
  • α = 90.00°
  • β = 97.3271(6)°
  • γ = 90.00°

List type: interleaving

List: 2D

Combined 3D structure and graph

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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: Br6 Re12 S16 (Br3 Re6 S8)

Multiplicity: 1

Coordination sequences:

  • 1, 8, 10, 13, 36, 29, 40, 54, 46, 75
  • 2, 16, 20, 22, 40, 30, 56, 70, 46, 62
  • 3, 12, 9, 27, 32, 30, 53, 49, 54, 83
  • 3, 12, 9, 27, 32, 34, 53, 45, 54, 83
  • 4, 19, 14, 16, 51, 46, 30, 60, 71, 69
  • 9, 10, 13, 36, 29, 40, 54, 46, 75, 72
  • 9, 11, 19, 31, 26, 47, 51, 51, 65, 74
  • 9, 12, 15, 28, 40, 40, 47, 48, 72, 79
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CIF datablock 1, entity 2 of 2

Basis: (1;0;0 0;0;1)

Dimensionality: 2

Formula: Br6 Re12 S16 (Br3 Re6 S8)

Multiplicity: 1

Coordination sequences:

  • 1, 8, 10, 13, 36, 29, 40, 54, 46, 75
  • 2, 16, 20, 22, 40, 30, 56, 70, 46, 62
  • 3, 12, 9, 27, 32, 30, 53, 49, 54, 83
  • 3, 12, 9, 27, 32, 34, 53, 45, 54, 83
  • 4, 19, 14, 16, 51, 46, 30, 60, 71, 69
  • 9, 10, 13, 36, 29, 40, 54, 46, 75, 72
  • 9, 11, 19, 31, 26, 47, 51, 51, 65, 74
  • 9, 12, 15, 28, 40, 40, 47, 48, 72, 79
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