Structure 9010718

9010717 << 9010718 >> 9010719
Original COD entry Download CIF Download DOT

Citation: Meerschaut, A.; Palvadeau, P.; Moello, Y.; Orlandi, P. (2001). Lead-antimony sulfosalts from Tuscany (Italy). IV. Crystal structure of pillaite, Pb9Sb10S23ClO0.5, an expanded monoclinic derivative of hexagonal Bi(Bi2S3)9I3, from the zinkenite group Locality: Buca della Vena mine, Tuscany, Italy Note: changed Pb2(z) to 0.2572 to match reported bond distances. European Journal of Mineralogy, 13, pp. 779-790.

Formula: Cl O0.5 Pb9.167 S23 Sb9.833

Cell parameters:

  • a = 49.49 Å
  • b = 4.1259 Å
  • c = 21.828 Å
  • α = 90°
  • β = 99.62°
  • γ = 90°

List type: interleaving

List: 1D

Combined 3D structure and graph

span 1 {1 1 1}
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JSmol combined CIF view

Linear Graph Knot

Molecules

CIF datablock 0, entity 1 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: O Pb4 S4 Sb3 (O Pb4 S4 Sb3)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 1, entity 2 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: O Pb4 S4 Sb3 (O Pb4 S4 Sb3)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 2, entity 3 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: O Pb4 S4 Sb3 (O Pb4 S4 Sb3)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 3, entity 4 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: O Pb4 S4 Sb3 (O Pb4 S4 Sb3)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 4, entity 5 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb S3 Sb2 (Pb S3 Sb2)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 5, entity 6 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb S3 Sb2 (Pb S3 Sb2)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 6, entity 7 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb S3 Sb2 (Pb S3 Sb2)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 7, entity 8 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb S3 Sb2 (Pb S3 Sb2)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 8, entity 9 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb2 S2 Sb2 (Pb S Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 9, entity 10 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb2 S2 Sb2 (Pb S Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 10, entity 11 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb2 S2 Sb2 (Pb S Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 11, entity 12 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb2 S2 Sb2 (Pb S Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 12, entity 13 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb S3 Sb (Pb S3 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 13, entity 14 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb S3 Sb (Pb S3 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 14, entity 15 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb S3 Sb (Pb S3 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 15, entity 16 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: Pb S3 Sb (Pb S3 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 16, entity 17 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb2 (S Sb)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 4, 2, 2, 4, 2, 2, 4
  • 2, 4, 2, 2, 4, 2, 2, 4, 2, 2
  • 3, 2, 3, 3, 2, 3, 3, 2, 3, 3
span 1 {1 1 1}

CIF datablock 17, entity 18 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb2 (S Sb)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 4, 2, 2, 4, 2, 2, 4
  • 2, 4, 2, 2, 4, 2, 2, 4, 2, 2
  • 3, 2, 3, 3, 2, 3, 3, 2, 3, 3
span 1 {1 1 1}

CIF datablock 18, entity 19 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb2 (S Sb)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 4, 2, 2, 4, 2, 2, 4
  • 2, 4, 2, 2, 4, 2, 2, 4, 2, 2
  • 3, 2, 3, 3, 2, 3, 3, 2, 3, 3
span 1 {1 1 1}

CIF datablock 19, entity 20 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb2 (S Sb)

Multiplicity: 1

Coordination sequences:

  • 2, 2, 2, 4, 2, 2, 4, 2, 2, 4
  • 2, 4, 2, 2, 4, 2, 2, 4, 2, 2
  • 3, 2, 3, 3, 2, 3, 3, 2, 3, 3
span 1 {1 1 1}

CIF datablock 20, entity 21 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 21, entity 22 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 22, entity 23 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 23, entity 24 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 24, entity 25 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 25, entity 26 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 26, entity 27 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 27, entity 28 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 28, entity 29 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 29, entity 30 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 30, entity 31 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}

CIF datablock 31, entity 32 of 32

Basis: (0;1;0)

Dimensionality: 1

Formula: S2 Sb (S2 Sb)

Multiplicity: 1

span 1 {1 1 1}